We have made excellent progress toward a practical route from field butanes to MTBE, the oxygenate of choice for high-octane, clean-burning, environmentally acceptable reformulated gasoline. We have evaluated two proprietary process possibilities with a potential commercial partner and have conducted a joint catalyst evaluation program. The first of the two potential processes considered during the past quarter utilizes a two-step route from isobutane to tert-butyl alcohol, TBA. Not only is TBA an intermediate for MTBE production but is equally applicable for ETBE-an oxygenate which utilizes renewable ethanol in its` manufacture. In the two-step process, isobutane is oxidized in a non-catalytic reaction to a roughly equal mixture of TBA and tert-butyl hydroperoxide. TBHP, eq. 1. We have developed an inexpensive new catalyst system based on an electron-deficient macrocyclic metal complex that selectively converts TBHP to TBA, eq. 2, and meets or exceeds all of the process criteria that we have set.
L o a d i n g
Organization
National Energy Technology Laboratory (NETL) - view all
Update frequencyunknown
Last updatedover 2 years ago
Format
Overviewkmd
Additional Information
KeyValue
CitationRoy Long, Catalytic conversion of light alkanes - phase V. Topical report, February 1993--October 1994, 2016-09-29, https://edx.netl.doe.gov/dataset/catalytic-conversion-of-light-alkanes-phase-v-topical-report-february-1993-october-1994
Netl Productyes
Poc EmailRoy.long@netl.doe.gov
Point Of ContactRoy Long
Program Or ProjectKMD
Publication Date1998-12-31
